Record Details

Design and synthesis of polycyclic sulfones via Diels-Alder reaction and ring-rearrangement metathesis as key steps

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Design and synthesis of polycyclic sulfones via Diels-Alder reaction and ring-rearrangement metathesis as key steps
 
Creator KOTHA, S
GUNTA, R
 
Subject DIVERSITY-ORIENTED APPROACH
HIGHLY STEREOSELECTIVE-SYNTHESIS
OLEFIN METATHESIS
STRATEGIC UTILIZATION
CATALYTIC METATHESIS
CLOSING METATHESIS
ORGANIC-SYNTHESIS
DERIVATIVES
STEREOCHEMISTRY
CYCLOADDITION
alkenylation
Diels-Alder reaction
ring-rearrangement metathesis
sulfones
 
Description Here, we describe a new and simple synthetic strategy to various polycyclic sulfones via Diels-Alder reaction and ring-rearrangement metathesis (RRM) as the key steps. This approach delivers tri- and tetracyclic sulfones with six (n = 1), seven (n = 2) or eight-membered (n = 3) fused-ring systems containing trans-ring junctions unlike the conventional all cis-ring junctions generally obtained during the RRM sequence. Interestingly the starting materials used are simple and commercially available.
 
Publisher BEILSTEIN-INSTITUT
 
Date 2016-01-15T10:38:47Z
2016-01-15T10:38:47Z
2015
 
Type Article
 
Identifier BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11,1373-1378
1860-5397
http://dx.doi.org/10.3762/bjoc.11.148
http://dspace.library.iitb.ac.in/jspui/handle/100/18367
 
Language en