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DIVERSITY ORIENTED APPROACH TO OXEPINE DERIVATIVES: FURTHER EXPANSION VIA DIELS-ALDER REACTION

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Title DIVERSITY ORIENTED APPROACH TO OXEPINE DERIVATIVES: FURTHER EXPANSION VIA DIELS-ALDER REACTION
 
Creator KOTHA, S
ALI, R
 
Subject MARINE NATURAL-PRODUCTS
KEY STEPS
CLAISEN REARRANGEMENT
ORGANIC-SYNTHESIS
OLEFIN METATHESIS
ENYNE METATHESIS
CYCLIC ETHERS
STRATEGY
TOXINS
RING
Oxepine
Diels-Alder Reaction
Rongalite
Sultine
Alkylation Reaction
 
Description Oxepine derivatives have been assembled via Diels-Alder (DA) reaction as a key step and the latent dienes suitable for the DA reaction have been generated in situ from the sultine derivatives, which in turn were achieved by using commercially available rongalite. The "drug like" molecules assembled here may find useful applications in medicinal as well as bioorganic chemistry.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2016-01-15T10:41:48Z
2016-01-15T10:41:48Z
2015
 
Type Article
 
Identifier HETEROCYCLES, 90(1)645-658
0385-5414
1881-0942
http://dx.doi.org/10.3987/COM-14-S(K)21
http://dspace.library.iitb.ac.in/jspui/handle/100/18373
 
Language en