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NEW APPROACH TO CYCLOPHANES CONTAINING ETHYLENEOXY BRIDGE BY GLASER-EGLINTON COUPLING

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Title NEW APPROACH TO CYCLOPHANES CONTAINING ETHYLENEOXY BRIDGE BY GLASER-EGLINTON COUPLING
 
Creator KOTHA, S
WAGHULE, GT
 
Subject DIVERSITY-ORIENTED APPROACH
RING-CLOSING METATHESIS
DIELS-ALDER REACTION
AMINO-ACID DERIVATIVES
ENYNE METATHESIS
KEY STEPS
ALKYNE METATHESIS
CROWN-ETHERS
MACRO RINGS
RONGALITE
 
Description Three strategies have been explored to generate cyclophane derivatives. In this regard, we identified alkyne metathesis, Diels-Alder reaction, and Glaser-Eglinton coupling as key steps. To this end, cyclophane derivatives containing ethyleneoxy bridge were successfully synthesized in four steps involving Glaser-Eglinton coupling and catalytic hydrogenation sequence.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2016-01-15T10:42:48Z
2016-01-15T10:42:48Z
2015
 
Type Article
 
Identifier HETEROCYCLES, 90(2)1289-1298
0385-5414
1881-0942
http://dx.doi.org/10.3987/COM-14-S(K)37
http://dspace.library.iitb.ac.in/jspui/handle/100/18375
 
Language en