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Structural and synthetic investigations on (2sf3s)-tetrahy dro-3-hy droxy-50x0-2,3-furandicarboxylic acid

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Title Structural and synthetic investigations on (2sf3s)-tetrahy dro-3-hy droxy-50x0-2,3-furandicarboxylic acid
 
Contributor Saud, I Ibnu
 
Subject Garcinia Acid
Tetrahydro
furandicarboxylica Acid
 
Description (2S,3S)-Tetrahydro-3-hydroxy-5-oxo-2,3-furandicarboxylica cid (Garcinia acid), a
newlinenaturally occurring hydroxy acid, has been identified as a potential chiral precursor.
newlineSimple procedure for the isolation of this compound from cheap natural sources have
newlinebeen developed Complete spectroscopic data of the molecule has been made
newlineavailable for the first time. Starting from (2S,3S)-Tetrahydro-3-hydroxy-5-0~0-2,3-
newlinefurandicarboxyllc acid, ton hitherto unknown chiral synthons including 1,2-diols have
newlinebeen prepared and character~sed. Asymmetric oxidations were performed to
newlinedemonstrate the catalytic efficiency of novel 1.2-diol ligands.
List of Publications 116p. and References p.106-115
 
Date 2010-08-03T12:01:54Z
2010-08-03T12:01:54Z
2010-08-03
May, 2000
 
Type Ph.D.
 
Identifier http://hdl.handle.net/10603/414
 
Language English US
 
Rights university
 
Format ix, 116p.
DVD
 
Publisher Kottayam
Mahatma Gandhi University
School Of Chemical Science
 
Source INFLIBNET