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Infrared spectroscopic study of the structural transitions of C60Br24

IR@CSIR-CFTRI

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Relation http://ir.cftri.com/1287/
JMS-01-97
 
Title Infrared spectroscopic study of the structural transitions of C60Br24
 
Creator Resmi, M.R.
George, L.
Singh, S.
Pradeep, T.
Udaya Sankar, K.
 
Subject 10 Spectroscopic and Spectrometric analysis
 
Description Variable temperature infrared spectroscopy and differential scanning calorimetry measurements show that C60Br24 under-goes two structural transitions at 171 and 180 K with AH values of 0.87 and 3.94 kJ mol-1 respectively. Only one transition is clearly visible in IR which is manifested by the hardening of certain IR peaks and narrowing of the 1400 cm-1 transition. The
results support an orientational change although ordering of the solvated bromine molecules could also be a reason for the observed changes.
 
Date 1997
 
Type Article
PeerReviewed
 
Format application/pdf
 
Language en
 
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Identifier http://ir.cftri.com/1287/1/Journal_of_Molecular_Structure_435_%281997%29_11-15.pdf
Resmi, M.R. and George, L. and Singh, S. and Pradeep, T. and Udaya Sankar, K. (1997) Infrared spectroscopic study of the structural transitions of C60Br24. Journal of Molecular Structure, 435. pp. 11-15.