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Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides.

IR@CSIR-CFTRI

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Relation http://ir.cftri.com/11645/
 
Title Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides.
 
Creator Santosh Kumar, S. C.
Manjunatha, J. R.
Srinivas, P.
Bettadaiah, B. K.
 
Subject 24 Organic Chemistry
 
Description Kinetic separation of trans-limonene oxide and trans-carvomenthene oxide was achieved in high
yield by selective ring opening of their cis-epoxides in the presence of InCl3 catalyst in water. Catalytic activity
of InCl3 was conserved up to 10 cycles. Nucleophilic addition of methanol in presence of InCl3 was also selective
as cis-epoxides preferentially reacted leaving behind trans-epoxides, which were separated by fractional
distillation.
 
Date 2014
 
Type Article
PeerReviewed
 
Format application/pdf
 
Language en
 
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Identifier http://ir.cftri.com/11645/1/J.%20Chem.%20Sci.%20126%283%29_2014_875.pdf
Santosh Kumar, S. C. and Manjunatha, J. R. and Srinivas, P. and Bettadaiah, B. K. (2014) Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides. Journal of Chemical Sciences, 126 (3). pp. 875-880.