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O-hydroxy Schiff bases derived from -hydroxy--methoxy benzaldehyde: Synthesis, x-ray studies and hydrogen bonding attributes

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Relation http://ir.cftri.com/12563/
http://dx.doi.org/10.1080/15421404.2015.1107814
 
Title O-hydroxy Schiff bases derived from -hydroxy--methoxy
benzaldehyde: Synthesis, x-ray studies and hydrogen
bonding attributes
 
Creator Amrutha Kala, A. L.
Nanishankar, V. Harohally
 
Subject 24 Organic Chemistry
 
Description The o-hydroxy Schiff bases consisting of N’-[(Z)-(2-hydroxy-4-
methoxyphenyl)methylidene]pyridine-4-carbohydrazide and N’-[(Z)-
(2-hydroxy-4-methoxyphenyl)methylidene]pyridine-3-carbohydrazide
were prepared by reaction of isonicotinic acid hydrazide and nicotinic
acid hydrazide by employing 2-hydroxy-4-methoxy benzaldehyde.
The spectroscopic techniques, X-ray crystal structure determination
as well as DFT calculations have been carried out to shed light on the
nature of hydrogen bonding. The both experimental and theoretical
investigations demonstrate the presence of intramolecular neutral
hydrogen bonding (enol-imine type) in these molecules.
 
Publisher
 
Date 2016
 
Type Article
PeerReviewed
 
Format application/pdf
 
Language en
 
Rights
 
Identifier http://ir.cftri.com/12563/1/MOLECULAR%20CRYSTALS%20AND%20LIQUID%20CRYSTALS_2016.pdf
Amrutha Kala, A. L. and Nanishankar, V. Harohally (2016) O-hydroxy Schiff bases derived from -hydroxy--methoxy benzaldehyde: Synthesis, x-ray studies and hydrogen bonding attributes. Molecular Crystals and Liquid Crystals, 629. pp. 146-157.