Record Details

Reactivity studies of eta sup (6)-p-cymene ruthenium(II) carboxylato complexes towards azide some neutral ligands

DRS at CSIR-National Institute of Oceanography

View Archive Info
 
 
Field Value
 
Title Reactivity studies of eta sup (6)-p-cymene ruthenium(II) carboxylato complexes towards azide some neutral ligands
 
Creator Singh, K.S.
Kollipara, M.R.
 
Subject p-cymene
ruthenium
azide
bipyridine
 
Description Mono and di-nuclear eta sup (6)-p-cymene ruthenium(II) complexes containing carboxylato ligand of formulation [(eta sup (6)-p-cymene)Ru(pa)Cl] and [{(eta sup (6)-p-cymene)RuCl}2 (mu-LL)] [where, pa = O sub (2)CC sub (6)H sub (4)-p-OMe (1), LL = C sub (2)O sub (4)(7) or C sub (2)CH sub (2)O sub (4)(10)] have been prepared by the reaction of [(p-cymene)RuCl sub (2)]sub (2) with the corresponding sodium salts of the carboxylic acids. Treatment of (eta sup (6)-p-cymene) ruthenium(II) carboxylato complexes with NaN sub (3) yielded azido complex [{(eta sup (6)-p-cymene)Ru(mu-N sub (3))Cl} sub (2)] whereas halide scavengers such as silver acetate, silvertrifluroacetate leads to the substitution of chlorine to give neutral complexes of formulation [{(eta sup (6)-p-cymene)RuY} sub (2)(mu-LL)](where, LL = bidentate carboxylate, Y = MeCO sub (2) or CF sub (3)CO sub (2)). Mono and di-cationic complexes were also been prepared by the treatment of complex 1 with the corresponding neutral ligands in the presence of AgBF sub (4). The complexes were fully characterized on the basis of microanalysis, FT-IR and NMR spectroscopic data
 
Date 2011-07-29T07:26:11Z
2011-07-29T07:26:11Z
2011
 
Type Journal Article
 
Identifier Journal of Indian Chemical Society, vol.88(4); 2011; 497-504
http://drs.nio.org/drs/handle/2264/3883
 
Language en
 
Rights Copyright [2011]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
 
Publisher The Indian Chemical Society