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Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds

DRS at CSIR-National Institute of Oceanography

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Title Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds
 
Creator Singh, K.S.
Kaminsky, W.
 
Subject ligands
alkynes
 
Description The arene ruthenium(II) azido compounds [{(p-cymene)Ru(N^O)N3}] have been prepared by the reaction of [{(p-cymene)Ru(mewN3)Cl}2] with the corresponding ligands. The ruthenium azido compounds [{(p-cymene)Ru(N^O)N3}] undergo 1,3-dipolar additions with substituted alkynes at room temperature to give the (eta6-arene) ruthenium triazolato compounds [(p-cymene)Ru(N^O){N3C2(CO2R)2}]. The compounds were characterized on the basis of FTIR, NMR (1H and 13C) and the molecular structure of a representative compound has been established with the help of single crystal X-ray diffraction.
 
Date 2014-02-05T10:03:41Z
2014-02-05T10:03:41Z
2014
 
Type Journal Article
 
Identifier Polyhedron, vol.68; 2014; 279–286
http://drs.nio.org/drs/handle/2264/4462
 
Language en
 
Rights An edited version of this paper was published by Elsevier. Copyright [2013] Elsevier
 
Publisher Elsevier