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Refractory metal nuggets in different types of cosmic spherules.

DRS at CSIR-National Institute of Oceanography

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Title Refractory metal nuggets in different types of cosmic spherules.
 
Creator Rudraswami, N.G.
ShyamPrasad, M.
Plane, J.M.C.
Berg, T.
Feng, W.
Balgar, S.
 
Subject Cosmic spherule
Seafloor
 
Description Out of the three basic cosmic spherule types collected from the seafloor, RMNs (refractory metal nuggets) have been reported from I-type spherules commonly, rarely from S-type spherules and never from the G-type spherules. Nuggets in the I-type cosmic spherules have formed by melting and complete oxidation during atmospheric entry, whereas no clear understanding emerged so far regarding the formation of the rare nuggets in S-type spherules. We collected cosmic spherules by raking the deep seafloor with magnets, and carried out systematic and sequential grinding, polishing and electron microscopic investigations on 992 cosmic spherules to identify RMNs. Fifty-four nuggets (RMNs) are identified, out of which 23, 26, and 5 nuggets are recovered from 23 I-, 21 S- and 5 G-type cosmic spherules, respectively. The nuggets in all the three spherule types follow a pattern indicative of their formation by metal segregation during atmospheric entry due to heating and oxidation, however, there are differences in their elemental distribution patterns. The refractory metal elements (RMEs) in the I-type spherules show a sequence of volatilization from a chondritic source, however, the relatively volatile RMEs in these spherules seem to be either depleted or distributed in numerous smaller nuggets. However, RMNs in the G-type spherules show closer conformity to CI chondrites and do not have a large volatile RME depletion. Whereas, the RMEs in the nuggets found in the S-type spherules are enriched in the volatile as well as the refractory elements. Also all the spherules show enrichment patterns and elemental ratios that are close to CI composition for refractory elements suggesting a common mechanism of formation. Pulse heating during atmospheric entry seems to be an efficient mechanism for RME segregation into nuggets. The patterns of RME enrichment and elemental ratios when compared with the nuggets in CAIs, show marked variations, outlining their differences in the process of formation. In addition, we also discovered a fremdling-like object in a cosmic spherule which has a nugget encased in Fe–Ni and sulfide phases, similar to those typically observed in CAIs of CV or CO chondrites. The atmospheric entry for this rare cosmic spherule appears to have taken place at a high zenith angle with a low entry velocity, so that its volatile phases are well preserved
 
Date 2014-04-07T08:56:08Z
2014-04-07T08:56:08Z
2014
 
Type Journal Article
 
Identifier Geochimica et Cosmochimica Acta, vol.131; 2014; 247-266
no
http://drs.nio.org/drs/handle/2264/4494
 
Language en
 
Relation Bioorg_Med_Chem_Lett_24_2863.jpg
 
Rights An edited version of this paper was published by Elsevier. Copyright [2014] Elsevier
 
Publisher Elsevier