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Syntheses, spectroscopic studies, crystal structure and complexation reactions of N- (2 or 4-hydroxylphenyl) benzaldimine

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Title Syntheses, spectroscopic studies, crystal structure and complexation reactions of N- (2 or 4-hydroxylphenyl) benzaldimine
 
Creator De, Rajib Lal
Mandal, Mahuya
Roy, Lovely
Mukherjee, Jaydeep
 
Description 207-213
Two monobasic bidentate Schiff base ligands (SBH) derived from the condensation reaction between benzaldehyde and 2-aminophenol (BENOPH) or 4-aminophenol (BENPAPH) have been subjected to complexation reactions stabilising the bis-ligated complexes MII(SB)₂ (MII=Cu, Ni, Co and Zn) where aminophenolic (-OH) groups participate in the complexation reaction. The newly synthesized Schiff bases and their complexes are characterized by elemental analysis, magnetic, spectroscopic and electrochemical studies. Crystal structure studies performed on BENPAPH show it to crystallize in the monoclinic form, space group P2₁/c; Z=4 with a, 6.500(7); b, 14.885(3); c, 10.852(2) Å and β, 91.489(12)º.
 
Date 2008-03-31T09:56:08Z
2008-03-31T09:56:08Z
2008-02
 
Type Article
 
Identifier 0376-4710
http://hdl.handle.net/123456789/589
 
Language en_US
 
Relation Int. Cl. ⁸ C07F1/08; C07F3/06; C07F15/04; C07F15/06
 
Publisher CSIR
 
Source IJCA Vol.47A(1) [February 2008]