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The reactions of polyhalogenated-2-nitro-1,3-butadiene with alkylthio, thiomorpholine and piperazine derivatives

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Title The reactions of polyhalogenated-2-nitro-1,3-butadiene with alkylthio, thiomorpholine and piperazine derivatives
 
Creator Ibis, Cemil
Deniz, N Gulsah
 
Subject N,S-substituted nitrodiene
Thioether
Piperazine derivatives
Thiomorpholine
Crystal structure
 
Description 1407-1413
Mono(thio)substituted-1,3-nitrodiene compounds 3a-c give 5a, 5c, 7a, 7c, 9a, 9c, 11a, 11c, 13a, 13b with thiomorpholine 4 and piperazine derivatives 6, 8, 10, 12. The new compound 3a is synthesized from reaction of 1 with 2a. The compound 7b crystallizes in the monolinic crystal system (space group P2₁/n) with the n-butyl group attached to S1 and C2Cl3 group disordered. The butadiene unit is not completely planar as can be expected if the two double bonds are fully conjugated. The structure has been solved by direct methods by using SHELXS-97 program and refined by using SHELXL-97 to the residul index R₁= 0.048.
 
Date 2008-09-15T10:03:45Z
2008-09-15T10:03:45Z
2008-09
 
Type Article
 
Identifier 0376-4699
http://hdl.handle.net/123456789/2002
 
Language en_US
 
Publisher CSIR
 
Source IJCB Vol.47B(9) [Sepetember 2008]