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Synthesis and characterisation of a new Schiff base and its metal complexes

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Title Synthesis and characterisation of a new Schiff base and its metal complexes
 
Creator Karaoğlan, Gülnur Keser
Avcıata, Ulvi
Gül, Ahmet
 
Description 1273-1276
A new Schiff base ligand, 2-(6-((E)-1-(2-heptadecylcarbonyl¬oxyphenyl)methylideneamino) [1,10] phenanthrolin-5-yl-imino¬methyl)phenyl stearate has been synthesised from the reaction of 5,6-bis(salicylideneimino)-1,10- phenanthroline with stearic acid. The ligand reacts with Co(II), Ni(II) and Cu(II) salts to form complexes. The ligand has been characterized by FTIR, ¹H NMR (DMSO-d₆), UV-vis and mass spectra, elemental analysis and fluorescence spectrophotometry. Protonation constants of the ligand and overall formation constants of the complexes have been calculated from potentiometric data using a computer program.
 
Date 2008-10-08T05:00:05Z
2008-10-08T05:00:05Z
2007-08
 
Type Article
 
Identifier 0376-4710
http://hdl.handle.net/123456789/2158
 
Language en_US
 
Relation Int. Cl.⁸ C07F1/08; C07F15/04; C07F15/06
 
Publisher CSIR
 
Source IJCA Vol.46A(8) (August 2007)