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Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)₂] system
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View Archive Info| Field | Value | |
| Title |
Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)₂] system
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| Creator |
Dutta, Daipayan
Jana, Atish Dipankar Ray, Ambarish |
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| Description |
1656-1660
Single crystal X-ray studies on a doubly carboxylate bridged {[Cu(pic)₂].2H₂O}ո (1) (pic = pyridine-2-carboxylate) polymeric chains extending along the crystallographic a axis reveal that adjacent polymeric chains are joined by the lattice water chains running parallel to the polymeric chain leading to a 2D sheet in the (101) plane. The successive sheets are interdigitated and glued to each other by a novel C=O…π interaction into a 3D supramolecular motif. The complex (1) can be regarded as a pseudo-polymorph of [Cu(pic)₂]ո which has been realized in two forms, violet (2) and blue-violet (3) from methanol. |
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| Date |
2008-12-05T05:41:17Z
2008-12-05T05:41:17Z 2008-11 |
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| Type |
Article
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| Identifier |
0376-4710
http://hdl.handle.net/123456789/2478 |
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| Language |
en_US
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| Relation |
C07F1/08
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| Publisher |
CSIR
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| Source |
IJCA Vol.47A(11) [November 2008]
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