Mössbauer study of nanoparticles of Co₀․₄Zn₀․₆Fe₂O₄
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Title |
Mössbauer study of nanoparticles of Co₀․₄Zn₀․₆Fe₂O₄
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Creator |
Dolia, S N
Prasad, Arun S Dhawan, M S Chander, Subhash Sharma, M P |
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Subject |
Nano-particles
Spinel ferrite Mössbauer spectra |
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Description |
826-829
Two samples of nanoparticles of Co₀․₄Zn₀․₆Fe₂O₄ with the average particle sizes of 6 nm and 15 nm have been synthesized by chemical co-precipitation method and followed by heat treatment at 600ºC. The cubic spinel structure in single phase has been confirmed by X-ray diffraction. The lattice parameters are 8.39 Å and 8.41 Å, respectively. ⁵⁷Fe Mössbauer spectra were recorded at 300 K and 80 K. Both samples are resolved in two patterns corresponding to two crystalline sites. The Mössbauer spectra and hysteresis curves for the two samples recorded at 300 K show superparamagnetic behaviour. The analysis of Mössbauer spectra reveal that the intensity of Fe³⁺ ions on both sites is nearly the same which indicate that the Zn²⁺ occupies the octahedral site in these samples. |
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Date |
2008-12-26T07:27:40Z
2008-12-26T07:27:40Z 2007-10 |
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Type |
Article
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Identifier |
0019-5596
http://hdl.handle.net/123456789/2674 |
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Language |
en_US
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Relation |
G01J3/28, H01F41/30
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Publisher |
CSIR
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Source |
IJPAP Vol.45(10) [October 2007]
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