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Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group

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Title Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
 
Creator Singh, Vishwakarma
Chandra, Girish
Mobin, Shaikh M
 
Subject Cycloaddition
Cyclohexa-2,4-dienone
Diels-Alder reaction
Bicyclo[2.2.2]octane
1,2-migration
 
Description 1886-1891
Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienones with ethyl vinyl ether, butyl vinyl ether, vinyl acetate and vinyl phenyl sulphone leading to a stereoselective entry into bicyclo[2.2.2]octanes having quaternary methyl group is reported. A novel thermal 1,2-methyl migration has also been described.
 
Date 2009-01-13T06:19:52Z
2009-01-13T06:19:52Z
2008-12
 
Type Article
 
Identifier 0376-4699
http://hdl.handle.net/123456789/2753
 
Language en_US
 
Publisher CSIR
 
Source IJCB Vol.47B(12) [December 2008]