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Synthesis, characterization and superoxide dismutase activity of a series of copper(II) complexes containing NNO donor Schiff base and benzimidazole ligands

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Title Synthesis, characterization and superoxide dismutase activity of a series of copper(II) complexes containing NNO donor Schiff base and benzimidazole ligands
 
Creator Patel, R N
 
Subject Coordination chemistry
Schiff bases
Imidazoles
Benzimidazoles
Copper
 
Description 173-180
Several mixed ligand copper(II) complexes, viz., [Cu(BPS)(ImH)](ClO4) (1), [Cu(BPS)(MeImH)](ClO₄) (2),
[Cu(BPS) (EtImH)](ClO₄) (3), [Cu(BPS)(BenzImH)]ClO4.0.5H₂O (4) and [Cu(BPS)(MeBenzImH)]ClO₄ (5), where
BPS = benzoylpyridine 4-phenylsemicarbazone, ImH = imidazole, MeImH = 2-methylimidazole,
EtImH = 2-ethylimidazole, BenzImH = benzimidazole, MeBenzImH = 2-methylbenzimidazole have been synthesized and characterized by the elemental analysis, molar conductance measurements, magnetic susceptibility measurements, FAB mass, IR, electronic, EPR spectral and cyclic voltammetric studies. The BenzImH complex (4) is structurally characterized by single crystal X-ray crystallography. Complex (4) crystallizes in the triclinic space group P-1 with unit cell parameters:
a = 10.104(3)Ǻ, b = 10.924(3)Ǻ, c = 13.128(3)Ǻ, ⍺ = 80.21(2)° , β = 70.63(3)°, ϒ = 89.61(2) and Z = 2. The one electron paramagnetic complexes show a d-d band near 700nm in DMSO and a cyclic voltammetric response due to Cu(II)/Cu(I) couple. The complexes show the presence of a distorted square planar CuN₂O₂ coordination geometry. Superoxide dismutase activity of the present complexes has also been studied.
 
Date 2009-02-12T10:20:37Z
2009-02-12T10:20:37Z
2009-02
 
Type Article
 
Identifier 0376-4710
http://hdl.handle.net/123456789/3112
 
Language en_US
 
Relation Int. Cl. ⁸ C07C251/02; C07F1/08
 
Source IJCA Vol.48A(2) [February 2009]