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Conformational analysis of some <i>N</i>-hydroxypiperidin-4-one oximes
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View Archive Info| Field | Value | |
| Title |
Conformational analysis of some N-hydroxypiperidin-4-one oximes
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| Creator |
Baskar, G
Gopalakrishnan, M Jabaraj, J Winfred |
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| Subject |
1H NMR
13C NMR NOESY conformation and N-hydroxypiperidone oximes |
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| Description |
580-584
Analysis of the spectral data (1H NMR and13C NMR) indicates that out of ten N-hydroxypiperidin-4-one oximes 3a-j, the compounds 3b and 3c exist predominantly in chair conformation with the aryl and alkyl substituents in the equatorial positions, whereas the compounds 3d-j exist in boat conformation. The introduction of an oxime group at C-4 causes a flattening of the ring about C(5)-C(6) bond. The NOESY spectrum (Nuclear Overhauser effect) recorded for the compound 3d further supports the assigned boat conformation. |
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| Date |
2009-04-17T04:26:55Z
2009-04-17T04:26:55Z 2009-04 |
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| Type |
Article
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| Identifier |
0376-4699
http://hdl.handle.net/123456789/3875 |
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| Language |
en_US
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| Publisher |
CSIR
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| Source |
IJC-B Vol.48B(04) [April 2009]
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