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SORPTION OF THREE PESTICIDES IN SOILS AS INFLUENCED BY CLAY AND SOIL ORGANIC

KrishiKosh

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Title SORPTION OF THREE PESTICIDES IN SOILS AS INFLUENCED BY CLAY AND SOIL ORGANIC
M Sc
 
Creator NEETHU NARAYANAN
 
Contributor V. T. Gajbhiye
 
Subject adsorption, pesticides, organochlorine compounds, concentrates, clay, organic matter, wood, irrigation, fractionation, extraction
 
Description T-8611
A multiresidue method for the analysis of three pesticides (chlorothalonil, chlorpyrifos
and pendimethalin) in soil and water by GC has been standardized. The instrument detection
limit was found to be 0.001μg/mL for the selected pesticides. Most efficient solvent for
extraction of these pesticides in water was DCM (dichloromethane) with an efficiency of 87.5-
90.9%. No clean up was required for water samples as they were free from interfering coextractives.
Dipping and shaking method using acetone was found to be the best for soil
extraction with efficiency of 83.7-89.6%. Amongst various adsorbents and solvent systems for
elution, alumina as an adsorbent and 50% acetone- hexane as eluent gave maximum efficiency
of 89.6-91.6%. Overall method recovery from soils ranged between 80.8-82%. The limit of
quantification for chlorothalonil, chlorpyrifos and pendimethalin was found to be 0.001 μg/mL
in water and 0.005 μg/g in soil.
 
Date 2016-09-21T19:54:07Z
2016-09-21T19:54:07Z
2012
 
Type Thesis
 
Identifier http://krishikosh.egranth.ac.in/handle/1/78240
 
Format application/pdf
 
Publisher IARI, DIVISION OF AGRICULTURAL CHEMICALS