Allyl tetrahydropyranyl ether: a versatile alcohol/thiol protecting reagent
IR@CSIR-IIIM
View Archive InfoField | Value | |
Title |
Allyl tetrahydropyranyl ether: a versatile alcohol/thiol protecting reagent
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Creator |
Kumar, Brijesh
Aga, Mushtaq A. Mukherjee, Debaraj Chimni, Swapandeep S. Taneja, Subhash C. |
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Subject |
Chemical Sciences
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Description |
Allyl tetrahydropyranyl ether (ATHPE) can be used as a versatile protecting reagent. In combination with NBS/I2, O-allyl group can easily be replaced by hydroxyls (including tertiary-OH) or thiols, in the molecules comprising other reactive functional groups such as halogen, nitro, acetonide and alkene under mild reaction conditions (near neutral pH and ambient temperature). |
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Date |
2009
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://iiim.csircentral.net/203/1/10.1016j.tetlet.2009.09.026.pdf
Kumar, Brijesh and Aga, Mushtaq A. and Mukherjee, Debaraj and Chimni, Swapandeep S. and Taneja, Subhash C. (2009) Allyl tetrahydropyranyl ether: a versatile alcohol/thiol protecting reagent. Tetrahedron Letters, 50 (46). pp. 6236-6240. ISSN 00404039 |
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Relation |
http://dx.doi.org/10.1016/j.tetlet.2009.09.026
http://iiim.csircentral.net/203/ |
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