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A Chemoselective Hydrogenation of the Olefinic Bond of a,b-Unsaturated Carbonyl Compounds in Aqueous Medium under Microwave Irradiation.

IR@CSIR-IHBT

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Title A Chemoselective Hydrogenation of the Olefinic Bond of
a,b-Unsaturated Carbonyl Compounds in Aqueous Medium
under Microwave Irradiation.
 
Creator Sharma, A
Kumar, Vinod
Sinha, Arun K
 
Subject Natural Product Chemistry
 
Description A microwave-assisted mild and ecofriendly
catalytic transfer hydrogenation process was developed
to reduce various a,b-unsaturated carbonyl
compounds into the corresponding saturated carbonyl
compounds in the presence of silica-supported palladium
chloride as catalyst and a combination of
MeOH/HCOOH/H2O (1 : 2 : 3) as hydrogen source
within 22 – 55 minutes in moderate to excellent yields
with 100% chemoselectivity
 
Publisher Wiley-V C H Verlag Gmbh , PO Box 10 11 61, D-69451 Weinheim, Germany .
 
Date 2006
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/165/1/advnce.pdf
Sharma, A and Kumar, Vinod and Sinha, Arun K (2006) A Chemoselective Hydrogenation of the Olefinic Bond of a,b-Unsaturated Carbonyl Compounds in Aqueous Medium under Microwave Irradiation. Advanced Synthesis Catalysis, 348 (3). pp. 354-360. ISSN 1615-4150
 
Relation http://ihbt.csircentral.net/165/