Record Details

Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers

IR@CSIR-IIIM

View Archive Info
 
 
Field Value
 
Title Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers
 
Creator Singh, Parvinder Pal
Gudup, Satish
Ambala, Srinivas
Singh, Umed
Dadhwal, Sumit
Singh, Baldev
Sawant, Sanghapal D.
Vishwakarma, Ram A.
 
Subject Chemical Sciences
 
Description We report a new and efficient iron oxide catalyzed crosscoupling reaction between organometallic species such as
alkyl/arylmagnesium halides or organolithium species and
a-hydrogen bearing cyclic aliphatic ethers via activation of
C(sp3)–H. This is the first example of iron oxide mediated direct C–C bond formation without expensive or toxic ligands.
 
Date 2011
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://iiim.csircentral.net/280/1/10.1039c1cc11094b.pdf
Singh, Parvinder Pal and Gudup, Satish and Ambala, Srinivas and Singh, Umed and Dadhwal, Sumit and Singh, Baldev and Sawant, Sanghapal D. and Vishwakarma, Ram A. (2011) Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers. Chemical Communications, 47 (20). p. 5852. ISSN 1359-7345
 
Relation http://dx.doi.org/10.1039/c1cc11094b
http://iiim.csircentral.net/280/