Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars
IR@CSIR-IIIM
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Title |
Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars
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Creator |
Thota, Niranjan
Mukherjee, Debaraj Reddy, Mallepally Venkat Yousuf, Syed Khalid Koul, Surrinder Taneja, Subhash Chandra |
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Subject |
Chemical Sciences
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Description |
A convenient and efficient method for selective replacement of the primary hydroxyl groups of sugars by chlorine with concomitant O-formylation, compatible with the presence of a variety of functional groups, has been developed using the Vilsmeier–Haack reaction. Sugars having free primary hydroxyl groups mostly afforded the chloro-O-formylated product while sugars devoid of primary hydroxyl groups yielded only O-formylated products.
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Date |
2009
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://iiim.csircentral.net/330/1/10.1039b900026g.PDF
Thota, Niranjan and Mukherjee, Debaraj and Reddy, Mallepally Venkat and Yousuf, Syed Khalid and Koul, Surrinder and Taneja, Subhash Chandra (2009) Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars. Organic & Biomolecular Chemistry, 7 (7). p. 1280. ISSN 1477-0520 |
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Relation |
http://dx.doi.org/10.1039/b900026g
http://iiim.csircentral.net/330/ |
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