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Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars

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Title Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars
 
Creator Thota, Niranjan
Mukherjee, Debaraj
Reddy, Mallepally Venkat
Yousuf, Syed Khalid
Koul, Surrinder
Taneja, Subhash Chandra
 
Subject Chemical Sciences
 
Description A convenient and efficient method for selective replacement of the primary hydroxyl groups of sugars by chlorine with concomitant O-formylation, compatible with the presence of a variety of functional groups, has been developed using the Vilsmeier–Haack reaction. Sugars having free primary hydroxyl groups mostly afforded the chloro-O-formylated product while sugars devoid of primary hydroxyl groups yielded only O-formylated products.
 
Date 2009
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://iiim.csircentral.net/330/1/10.1039b900026g.PDF
Thota, Niranjan and Mukherjee, Debaraj and Reddy, Mallepally Venkat and Yousuf, Syed Khalid and Koul, Surrinder and Taneja, Subhash Chandra (2009) Reaction of carbohydrates with Vilsmeier reagent: a tandem selective chloro O-formylation of sugars. Organic & Biomolecular Chemistry, 7 (7). p. 1280. ISSN 1477-0520
 
Relation http://dx.doi.org/10.1039/b900026g
http://iiim.csircentral.net/330/