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One-Pot Two-Step Oxidative Cleavage of 1,2-Arylalkenes to Aryl Ketones Instead of Arylaldehydes in an Aqueous Medium: A Complementary Approach to Ozonolysis

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Field Value
 
Title One-Pot Two-Step Oxidative Cleavage of 1,2-Arylalkenes to Aryl Ketones
Instead of Arylaldehydes in an Aqueous Medium: A Complementary Approach
to Ozonolysis
 
Creator Sharma, N
Sharma, A
Kumar, R
Shard, A
Sinha, Arun K
 
Subject Natural Product Chemistry
 
Description A new approach has been developed for a one-pot and selective
oxidative cleavage of aryl- and 1,2-diarylalkenes leading
to one-carbon shorter aryl ketones; thereby, providing a complementary
approach to classical ozonolysis. The methodology
was applicable to diverse aromatic and polyaromaticarylalkenes bearing electron-donating or -withdrawing
groups on the aromatic ring. The protocol also provided a
useful one-pot oxidative cleavage–condensation sequence,
which could potentially have important applications in natural
product total synthesis.
 
Date 2010
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/285/1/560_2010_One-pot_two-step.pdf
Sharma, N and Sharma, A and Kumar, R and Shard, A and Sinha, Arun K (2010) One-Pot Two-Step Oxidative Cleavage of 1,2-Arylalkenes to Aryl Ketones Instead of Arylaldehydes in an Aqueous Medium: A Complementary Approach to Ozonolysis. European Jpurnal of Organic Chemistry. pp. 6025-6032.
 
Relation http://ihbt.csircentral.net/285/