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Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction

IR@CSIR-IIIM

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Field Value
 
Title Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction
 
Creator Kumar, Manjeet
Shah, Bhahwal A.
Taneja, Subhash C.
 
Subject Chemical Sciences
 
Description The lipase Novozym435 (0.6% w/w) was used in tandem with organocatalysts in a first vinyl/isopropenyl acetate-mediated aldol reaction. The reaction was facilitated through the lipase-catalyzed in situ generation of acetaldehyde/acetone. The importantfeatures of the present methodology include the mild and facile reaction conditions, regenerability of the lipase, comparatively high yields and minimal side product formation.
 
Date 2011
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://iiim.csircentral.net/359/1/10.1002adsc.201000980.pdf
Kumar, Manjeet and Shah, Bhahwal A. and Taneja, Subhash C. (2011) Tandem Catalysis by Lipase in a Vinyl Acetate-Mediated Cross-Aldol Reaction. Advanced Synthesis & Catalysis, 353 (8). pp. 1207-1212. ISSN 16154150
 
Relation http://dx.doi.org/10.1002/adsc.201000980
http://iiim.csircentral.net/359/