ICAR Research Data Repository for Knowledge Management
Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis acid catalysis
IR@CSIR-IHBT
View Archive Info| Field | Value | |
| Title |
Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis acid catalysis |
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| Creator |
Singh , Bikram
Jaitak, V Kaul, V K |
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| Subject |
Natural Product Chemistry
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| Description |
Acylation of bita-caryophyllene, a sesquiterpene hydrocarbon with acetic anhydride, was carried out under mild catalytic conditions using Lewis acids such as BF3. Et2O, ZnCl2, FeCl3, I2 and AlCl3 as catalysts. Among these, BF3. Et2O was found to catalyse the reaction most efficiently, yielding three acylated products in 75% yield under solvent-free conditions. The structures were confirmed by NMR and MS techniques. |
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| Date |
2009
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/319/2/399_2009_Synthesis.pdf
Singh , Bikram and Jaitak, V and Kaul, V K (2009) Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis acid catalysis. Natural Product Research , 23 (15). pp. 1445-1450. |
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| Relation |
http://ihbt.csircentral.net/319/
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