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A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone

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Title A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone
 
Creator Sinha, Arun K
Acharya , Ruchi
Joshi, B P
 
Subject Natural Product Chemistry
 
Description Oxidation of beta-asarone (2) with DDQ gave trans-2,4,5-trimethoxycinnainaldehyde (3), which on treatment with p-toluenesulfonyl hydrazine provided corresponding alpha,beta-unsaturated hydrazone derivative (4). Reduction of 4 with sodium borohydride in acetic acid afforded gamma-asarone (1) in 43% yield.
 
Publisher American Chemical Society, 1155 16TH ST, NW, Washington, DC 20036 USA
 
Date 2002
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/365/1/64_A_A_Mild.pdf
Sinha, Arun K and Acharya , Ruchi and Joshi, B P (2002) A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone. Journal of Natural Products , 65 (5). pp. 764-765. ISSN 0163-3864
 
Relation http://ihbt.csircentral.net/365/