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Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst

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Field Value
 
Title Phosphane-Free Green Protocol for Selective Nitro Reduction
with an Iron-Based Catalyst
 
Creator Sharma, U
Verma, P K
Kumar, Neeraj
Kumar, Vishal
Bala , M
Singh , Bikram
 
Subject Plant sciences
Natural Product Chemistry
 
Description Abstract: Iron phthalocyanine with
iron sulfate has been successfully applied
for high chemo- and regioselective
reduction of aromatic nitro compounds
to give the corresponding
amines in a green solvent system without
using any toxic ligand. The catalytic
systems were also compatible with a
large range of other reducible functional
groups, such as keto, acid, amide,
ester, halogen, lactone, nitrile, Nbenzyl,
O-benzyl, hydroxy, and heterocycles.
In the present study, dinitro
compounds have been regioselectively
reduced to the corresponding amines
with high yield. In most of the cases
the conversion and selectivity was
greater than 99% as determined by
GC-MS analysis.
 
Date 2011
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/947/1/08-02-2012_Phosphane-free.pdf
Sharma, U and Verma, P K and Kumar, Neeraj and Kumar, Vishal and Bala , M and Singh , Bikram (2011) Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst. Chemistry-A European Journal , 17. pp. 5903-5907.
 
Relation http://ihbt.csircentral.net/947/