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Ligand-free solid supported palladium(0) nano/microparticles promoted C–O, C–S, and C–N cross coupling reaction

IR@CSIR-IHBT

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Title Ligand-free solid supported palladium(0) nano/microparticles promoted C–O,
C–S, and C–N cross coupling reaction
 
Creator , Bandna
Guha, Nitul Ranjan
Shil, Arun K
Sharma , Dharminder
Das, Pralay
 
Subject Plant sciences
Natural Product Chemistry
 
Description Ligand-free solid-supported nano and microparticles of Pd(0) (SS-Pd) were used as a heterogeneous catalyst
in carbon-heteroatom bond formation reactions. Nitro substituted aryl halides reacted with oxygen,
sulfur, and nitrogen nucleophiles to afford the corresponding products in good yields. A one-pot sequential
cross coupling and nitro-reduction was also performed using the same SS-Pd catalyst to access amine
substituted carbon-heteroatomic molecules. In addition, SS-Pd could be recycled up to seven runs without
a significant loss of catalytic activity
 
Date 2012
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/1220/1/25_Ligand-free.pdf
, Bandna and Guha, Nitul Ranjan and Shil, Arun K and Sharma , Dharminder and Das, Pralay (2012) Ligand-free solid supported palladium(0) nano/microparticles promoted C–O, C–S, and C–N cross coupling reaction. Tetrahedron Letters, 53. pp. 5318-5322.
 
Relation http://ihbt.csircentral.net/1220/