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Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for chemoselective reduction of nitroarenes

IR@CSIR-IHBT

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Field Value
 
Title Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for
chemoselective reduction of nitroarenes
 
Creator Shil, Arun K
Sharma, Dharminder
Guha, Nitul Ranjan
Das, Pralay
 
Subject Natural Product Chemistry
 
Description Solid supported palladium(0) (SS-Pd) catalyzed highly chemoselective reduction of nitroarenes to the
corresponding anilines was accomplished under a milder reaction condition. This catalyst showed high
compatibility with various reducing agents (NaBH4, Et3SiH, and NH2NH2∙H2O) and a large number of
reducible functional groups such as sulfonamide, amides, carboxylic acid, ester, alcohol, halide, hetero
cycle, nitrile, alkene, carbonyl, O-benzyl, and N-benzyl were tolerated. Most of the reactions were clean
and high yielding. The SS-Pd catalyst could be recycled up to seven runs without significant loss of
activity
 
Date 2012
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/1233/1/37_Solid_supported_Rh.pdf
Shil, Arun K and Sharma, Dharminder and Guha, Nitul Ranjan and Das, Pralay (2012) Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for chemoselective reduction of nitroarenes. Tetrahedron Letters, 53. pp. 4858-4861.
 
Relation http://ihbt.csircentral.net/1233/