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Solid-Supported Rhodium(0) Nano-/Microparticles: An Efficient Ligand-Free Heterogeneous Catalyst for Microwave-Assisted Suzuki–Miyaura Cross-Coupling Reaction

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Title Solid-Supported Rhodium(0) Nano-/Microparticles: An Efficient
Ligand-Free Heterogeneous Catalyst for Microwave-Assisted
Suzuki–Miyaura Cross-Coupling Reaction
 
Creator Guha, Nitul Ranjan
Reddy, Chennayala Bal
Aggarwal, Nidhi
Sharma , Dharminder
Shil, Arun K
------,, Bandna
Das, Pralay
 
Subject Plant sciences
Synthetic Chemistry
 
Description Solid-supported nano- and microparticles
of rhodium(0) (SS-Rh) were prepared and applied
as a ligand free heterogeneous catalyst for Suzuki–
Miyaura cross-coupling reaction with wide range of
substrate scope. A hitherto unknown Rh-catalyzed
Suzuki cross-coupling reaction of aldehyde and cyanohaloarenes
was observed rather than the usual
nucleophilic arylation.The catalyst can be removed
by simple filtration and recycled upto twelve runs
without any deterioration of activity.
 
Date 2012
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://ihbt.csircentral.net/1305/1/76.Solid_supported_Rh%280%29.pdf
Guha, Nitul Ranjan and Reddy, Chennayala Bal and Aggarwal, Nidhi and Sharma , Dharminder and Shil, Arun K and ------,, Bandna and Das, Pralay (2012) Solid-Supported Rhodium(0) Nano-/Microparticles: An Efficient Ligand-Free Heterogeneous Catalyst for Microwave-Assisted Suzuki–Miyaura Cross-Coupling Reaction. Journal of the Advanced Synthesis & Catalysis, 354. pp. 2911-2915.
 
Relation http://ihbt.csircentral.net/1305/