ICAR Research Data Repository for Knowledge Management
An all-anti conformation of the β-ala moiety in the crystalline state
DIR@IMTECH: CSIR-Institute of Microbial Technology
View Archive Info| Field | Value | |
| Title |
An all-anti conformation of the β-ala moiety in the crystalline state
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| Creator |
Thakur, A K
Kishore, Raghuvansh |
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| Subject |
QD Chemistry
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| Description |
In marked contrast to the most favourable folded conformation, predicted from ab initio quantum mechanical calculations, the crystal structure analysis of the model system incorporating CONHCH2CH2CONH moiety, revealed the existence of an all-anti conformation, characterized by the backbone torsion angles: φ ≈ −146°, μ ≈ 172° and ψ ≈ 155°. Potential applications of the residue to form highly ordered, novel β-sheet like structure(s) with distinct faces have been suggested.
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| Publisher |
Elsevier Science
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| Date |
1999
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://crdd.osdd.net/open/798/1/kishore1999.1.pdf
Thakur, A K and Kishore, Raghuvansh (1999) An all-anti conformation of the β-ala moiety in the crystalline state. Tetrahedron Letters, 40 (27). pp. 5091-5094. ISSN 00404039 |
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| Relation |
http://dx.doi.org/10.1016/S0040-4039(99)00989-2
http://crdd.osdd.net/open/798/ |
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