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Decolorization and degradation of H-acid and other dyes using ferrous–hydrogen peroxide system

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Title Decolorization and degradation of H-acid and other dyes
using ferrous–hydrogen peroxide system
 
Creator Sophia, Carmalin A
Swaminathan, K
Sandhya, S
Pachhade,, K
Subrahmanyam, Y V
 
Subject Industrial wastewater Characteristics
Industrial Wastewater Treatment & Disposal
Environmental Pollution
Water Pollution
 
Description In this study, advanced oxidation process utilizing Fenton�s reaction was investigated for the decolorization and
degradation of two commercial dyes viz., Red M5B, Blue MR and H-acid, a dye intermediate used in chemical industries
for the synthesis of direct, reactive and azo dyes. Effect of Fe2þ, H2O2, pH, and contact time on the degradation
of the dyes was studied. Maximum color and COD removal was obtained for Red M5B, H-acid and Blue MR at 10–25
mg/l of Fe2þ dose and 400–500 mg/l of H2O2 dose at pH 3.0. The initial oxidation reaction was found to fit into first
order rate kinetics and the rate of oxidation of H-acid was higher than the other dyes. Release of chloride and sulfate
from the Fenton�s treated Red M5B dye and sulfate from H-acid and Blue MR indicates that the dye degradation
proceeds through cleavage of the substituent group
 
Publisher Elsevier
 
Date 2003-02
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://neeri.csircentral.net/437/1/dye.pdf
Sophia, Carmalin A and Swaminathan, K and Sandhya, S and Pachhade,, K and Subrahmanyam, Y V (2003) Decolorization and degradation of H-acid and other dyes using ferrous–hydrogen peroxide system. Chemosphere, 50 (5). pp. 619-623. ISSN 0045-6535
 
Relation http://www.sciencedirect.com/science/article/pii/S004565350200615X
http://neeri.csircentral.net/437/