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Field | Value |
Title | Palladium-Catalyzed Directed para C-H Functionalization of Phenols |
Names |
PATRA, T
BAG, S KANCHERLA, R MONDAL, A DEY, A PIMPARKAR, S AGASTI, S MODAK, A MAITI, D |
Date Issued | 2016 (iso8601) |
Abstract | Various practical methods for the selective C-H functionalization of the ortho and recently also of the meta position of an arene have already been developed. Following our recent development of the directing-group-assisted para C-H functionalization of toluene derivatives, we herein report the first remote para C-H functionalization of phenol derivatives by using a recyclable silicon-containing biphenylbased template. The effectiveness of this strategy was illustrated with different synthetic elaborations and by the synthesis of various phenol-based natural products. |
Genre | Article |
Topic | U-SHAPED TEMPLATE |
Identifier | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(27)7751-7755 |