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| Field | Value |
| Title | Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation |
| Names |
HALDER, A
KANDAMBETH, S BISWAL, BP KAUR, G ROY, NC ADDICOAT, M SALUNKE, JK BANERJEE, S VANKA, K HEINE, T VERMA, S BANERJEE, R |
| Date Issued | 2016 (iso8601) |
| Abstract | Two new chemically stable triazine- and phenylcore-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs. |
| Genre | Article |
| Topic | COVALENT ORGANIC FRAMEWORK |
| Identifier | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(27)7806-7810 |