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Production of hydrogen-rich gas via reforming of iso-octane over Ni–Mn and Rh–Ce bimetallic catalysts using spray pulsed reactor

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Title Production of hydrogen-rich gas via reforming of iso-octane over
Ni–Mn and Rh–Ce bimetallic catalysts using spray pulsed reactor
 
Creator Biniwale, Rajesh
Ichikawa, N Kariya Masaru
 
Subject Materials Science
 
Description The conversion of hydrocarbon fuels such as gasoline and diesel is a potential source for hydrogen production towards various
fuel cell systems. A novel spray pulsed mode reactor to create alternate wet and dry conditions on the catalyst surface has been used
in this study to enhance the rates of hydrogen production compared with the solid-gas phase reaction due to the improvement of
the catalyst reactant contact. The production of hydrogen-rich gas by reforming of iso-octane (2,2,4-trimethylepentane) in the
presence of steam and air has been studied at 600 and 700 �C over Ni–Mn and Rh–Ce bimetallic catalysts supported on alumina
mesh. The feed rate of iso-octane was varied from 0.553 to 5.53 m mol min)1 by controlling pulse injection in terms of the width
and frequency of injection of iso-octane. Based on the product analysis optimized condition for higher hydrogen production and
high H2/CO ratio has been deduced.
 
Publisher Springer
 
Date 2005
 
Type Article
NonPeerReviewed
 
Format application/pdf
 
Identifier http://neeri.csircentral.net/1052/1/Catalysis%20letter%20100%202005.pdf
Biniwale, Rajesh and Ichikawa, N Kariya Masaru (2005) Production of hydrogen-rich gas via reforming of iso-octane over Ni–Mn and Rh–Ce bimetallic catalysts using spray pulsed reactor. Catalysis Letters, 100 (1-2). pp. 17-25. ISSN 1011-372X (Print) 1572-879X (Online)
 
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http://neeri.csircentral.net/1052/