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Nonequilibrium Fluctuations, Quantum Optical Responses and Thermodynamics of Molecular Junctions

Electronic Theses of Indian Institute of Science

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Title Nonequilibrium Fluctuations, Quantum Optical Responses and Thermodynamics of Molecular Junctions
 
Creator Goswami, Himangshu Prabal
 
Subject Nonequilibrium Fluctuations
Molecular Junctions
Electron Transfer Statistics
Density Vector
Fock Space
Liouville Space
Quantum Junctions
Quantum Optical Response
Quantum Heat Engines
Thermal Fluctuations
Quantum Dot Junctions
Thermodynamics
Inorganic and Physical Chemistry
 
Description Mankind has come a long way since the invention of wheel to accessing information in the quintillionth of a second. At the heart of every invention ever made, there has been only one objective, to ease the way of living. The progeny of this philosophy automatically came to be known as technology. It was technology that led to the design of the wheel for fast human transportation and the same motivation let him design more sophisticated machines. In mankind’s journey to improve technology, it began to learn efficient or correct ways to utilize and understand resources around it, creating a whole new philosophy called science. Ingeniously, it was science that let humans understand what they were made of: matter, to discovering what matter itself was composed of: atoms and what puts these together: forces. Science and technology has been of tremendous comfort for mankind and has helped it evolve throughout history. However, it is not always that science and technology go hand in hand. Technology has always helped man design devices and instruments which often bring physical comfort. Science on the other hand has made sure that loss in manual labor is compensated by increased inquisitiveness.
There were times when technology was more developed than science. This was the time when machines were taking mankind by fire, resulting in the first and second industrial revolutions. During that same time, science was develop-ing slowly by increasing human curiosity to learn the way nature functioned at finer details. This led to the discovery of the electron by Joseph John Thomson, who proved the electron to be a negatively charged particle. Consequently, he was awarded the 1906 Nobel Prize in Physics for his work on electricity conduction in gases. Later, his son, George Paget Thomson, counter-proved that electrons are actually waves. He was also awarded the 1937 Nobel Prize in Physics, along with Clinton Joseph Davisson for their discovery of electron diffraction caused by crystals. Despite the ambiguity, mankind today accepts electrons to have dual properties. It is both a wave and a particle. This duality is not limited to electrons but is applicable to all matter, as proposed by Louis de Broglie and is one of the fundamental principles in science. With the help of well-developed technology, mankind can now design machines that allow controlled flow of electrons establishing the world of electronics, allowing faster human communication. The study of electronic properties and its usage in designing efficient devices is what electronics is all about. Electrons are the protagonist of mankind today. The presence of electrons is unanimously accepted by everyone. All physical and chemical processes are a result of electrons getting transported. Electron transfer processes are ubiquitous in nature, be it in photosynthesis or energy production in mitochondria . It is the fundamental process in all chemical reactions and all physical processes related to electricity. Every piece of hi-tech gadget practically uses the electron, and the whole of humanity is being serviced by it. In fact, a life without utilizing the electrons is abysmally mundane. Electronics has evolved from designing the first millimeter sized point contact transistor to silicon chip processors that contain billions of nanosized transistors. Studying electron transport has also led to the discovery of light emission during conduction popularly known as LED, an abbreviation for light emitting diode. Heating up of devices during electron transport forced mankind to study heat transport and design materials that have highly efficient electron transfer processes. Electron transfer is also the basic principle behind the Scanning Tunneling Microscope (STM), Scanning Electron Microscope (SEM) and the Transmission Electron Microscope (TEM) which replaced the conventional idea of using light (photons) as a source to observe matter at the nanolevel.
However, mankind is still in the process of developing a technology which exploits both properties of the electron simultaneously. Today, science and technology work together to overcome this barrier. Indeed, science and technology today have come as far as controlling electron transport up to a single atomic level where quantum effects (discretization and interference of states that make up the system) are very pronounced. This branch can be referred to as quantum electronics or quantronics. It is one of the possible alternatives to conventional silicon based electronics, and is made of three separate fields. The first one that exploits the quantum nature of electron transport in nanoscopic systems, is usually called molecular electronics or moletronics. The second involves ex-ploiting the spin of the electron and is termed as spintronics. The third is the most challenging where neither science nor technology has been able to fully grasp the characteristics, i.e utilizing the heat quanta in designing thermal de-vices at the single atomic level. In general, for ultimate exploitation of both the wave and particle characteristics of the electron, a proper comprehension of the quantum effects during electron transport is necessary to design a quantronic device. Also, in any quantronic device, apart from quantum effects, fluctuations in temperature cause changes in the flow of electrons. Since electron flow is a random process, fluctuations need to be analyzed from a statistical point of view. Moreover, to address issues related to efficiency and power of these quantronic devices, a proper understanding of the thermodynamic aspects is required.
The aim of the work in the thesis is to theoretically analyze the fluctuations, quantum effects and thermodynamics, that in principle, affect the basic physics and chemistry during electron and heat transport in a specific class of out of equilibrium quantum systems. This class of quantum systems are prototypes for designing quantronic devices, where both wave and particle nature of the electrons are pronounced. These are called molecular junctions or quantum junctions. It will in turn help the field of quantronics in the long run. However, in this thesis, it is the science that I address and not the technological aspects.
 
Contributor Harbola, Upendra
 
Date 2018-02-06T16:56:18Z
2018-02-06T16:56:18Z
2018-02-06
2016
 
Type Thesis
 
Identifier http://hdl.handle.net/2005/3063
http://etd.ncsi.iisc.ernet.in/abstracts/3928/G27747-Abs.pdf
 
Language en_US
 
Relation G27747