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Field | Value |
Title | Rhodium-Catalyzed meta-C-H Functionalization of Arenes |
Names |
BERA, M
AGASTI, S CHOWDHURY, R MONDAL, R PAL, D MAITI, D |
Date Issued | 2017 (iso8601) |
Abstract | Rhodium-catalyzed ortho-C-H functionalization is well known in the literature. Described herein is the Xphos-supported rhodium catalysis of meta-C-H olefination of benzylsulfonic acid and phenyl acetic acid frameworks with the assistance of a para-methoxy-substituted cyano phenol as the directing group. Complete mono-selectivity is observed for both scaffolds. A wide range of olefins and functional groups attached to arene are tolerated in this protocol. |
Genre | Review |
Topic | AMINO-ACID LIGANDS |
Identifier | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(19)5272-5276 |