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Title Rhodium-Catalyzed meta-C-H Functionalization of Arenes
 
Names BERA, M
AGASTI, S
CHOWDHURY, R
MONDAL, R
PAL, D
MAITI, D
Date Issued 2017 (iso8601)
Abstract Rhodium-catalyzed ortho-C-H functionalization is well known in the literature. Described herein is the Xphos-supported rhodium catalysis of meta-C-H olefination of benzylsulfonic acid and phenyl acetic acid frameworks with the assistance of a para-methoxy-substituted cyano phenol as the directing group. Complete mono-selectivity is observed for both scaffolds. A wide range of olefins and functional groups attached to arene are tolerated in this protocol.
Genre Review
Topic AMINO-ACID LIGANDS
Identifier ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(19)5272-5276