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<strong>Macrocyclic divalent transition metal complexes of cobalt, nickel, copper and zinc with their antimicrobial, spectroscopic studies</strong>

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Title Statement <strong>Macrocyclic divalent transition metal complexes of cobalt, nickel, copper and zinc with their antimicrobial, spectroscopic studies</strong>
 
Added Entry - Uncontrolled Name Sharma, Kavita ; National Institute of Technology Kurukshetra-136118
Singh, Prof. Dharam Pal; Head of Department, Department of Chemistry, National Institute of Technology,Kurukshetra-136119
Kumar, Dr.Vikas ; Department of Microbiology, Kurukshetra University, Kurukshetra- 136119, India
 
Uncontrolled Index Term Antimicrobial; Macrocyclic metal complexes; Octahedral geometry; Schiff base
 
Summary, etc. A series of tetra dentate macrocyclic metal complexes [M (C<sub>16</sub>H<sub>12</sub>N<sub>8</sub>) X<sub>2</sub>] have been synthesized by template condensation of diaminomaleonitrile and diacetyl in presence of divalent metal ions where M= Co<sup>II</sup>, Ni<sup>II</sup>, Cu<sup>II</sup>, Zn<sup>II</sup> and X= Cl<sup>-1</sup>, NO<sub>3</sub><sup>-1</sup>, CH<sub>3</sub>COO<sup>-1</sup>. Metal complexes are characterized by elemental analysis, conductance measurements, magnetic susceptibility measurements, IR, Far IR, NMR, ESR, electronic and mass spectra. Based on the molecular modeling studies and various spectral studies, distorted octahedral geometry has been proposed for metal complexes. All the complexes show low conductance values which indicate their non-electrolytic nature. Antimicrobial activities of macrocyclic complexes have been carried out <em>in vitro</em> against gram positive bacteria, gram negative bacteria and fungal strains showing good results as compare with standard drugs
 
Publication, Distribution, Etc. Indian Journal of Chemical Technology (IJCT)
2018-07-05 10:41:26
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCT/article/view/16384
 
Data Source Entry Indian Journal of Chemical Technology (IJCT); ##issue.vol## 24, ##issue.no## 5 (2017): Indian Journal of Chemical Technology
 
Language Note en