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A Modified Synthetic Approach to Optically Pure Benzoxazepines from Amino Acid Precursors Using Intramolecular Buchwald–Hartwig C–O Bond-Formation Reaction

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Title A Modified Synthetic Approach to Optically Pure Benzoxazepines from Amino Acid Precursors Using Intramolecular Buchwald–Hartwig C–O Bond-Formation Reaction
 
Creator Bhattacharya, Debleena
Behera, Ashok
Hota, Sandip K
Chattopadhyay, Partha
 
Subject Chemistry
 
Description Palladium-catalyzed intramolecular aryl etherification
reaction using bulky binaphthylphosphane ligand is shown to be a
convenient method for the synthesis of seven-membered heterocycles.
Application of this methodology to a naturally occurring proteinogenic
L-amino acid has led to the synthesis of optically active
benzoxazepine ring systems of versatile biological importance
 
Date 2011
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/83/1/SYNTHESIS%2DSTUTTGART%2C4%2C585%2D592%2C2011[90].pdf
Bhattacharya, Debleena and Behera, Ashok and Hota, Sandip K and Chattopadhyay, Partha (2011) A Modified Synthetic Approach to Optically Pure Benzoxazepines from Amino Acid Precursors Using Intramolecular Buchwald–Hartwig C–O Bond-Formation Reaction. SYNTHESIS (4). pp. 585-592.
 
Relation http://dx.doi.org/10.1055/s-0030-1258406
http://www.eprints.iicb.res.in/83/