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Radical Cyclization of Exo-Methylene Furanose Derivatives: an Expedient approach to the Synthesis of Chiral Tricyclic Nucleosides and Benzannulated Oxepine Derivatives.

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Title Radical Cyclization of Exo-Methylene Furanose Derivatives: an Expedient approach to the Synthesis of Chiral Tricyclic
Nucleosides and Benzannulated Oxepine Derivatives.
 
Creator Neogi, Arpita
Majhi, Tirtha Pada
Ghoshal, Nanda
Chattopadhyay, Partha
 
Subject Chemistry
 
Description Abstract—Tributyltin radical mediated cyclization of the glucose derived exo-methylene furanose derivatives 5a–c led to the highly
functionalized cis-fused bicyclic ethers 6a–c. The product could subsequently be transformed to the optically active tricyclic nucleoside
analogue 8 or oxepine derivative 9.
 
Publisher Elsevier
 
Date 2005
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/330/1/TETRAHEDRON_61(_39)_9368%2D93742005[19].pdf
Neogi, Arpita and Majhi, Tirtha Pada and Ghoshal, Nanda and Chattopadhyay, Partha (2005) Radical Cyclization of Exo-Methylene Furanose Derivatives: an Expedient approach to the Synthesis of Chiral Tricyclic Nucleosides and Benzannulated Oxepine Derivatives. Tetrahedron, 61 (39). pp. 9368-9374.
 
Relation http://dx.doi.org/10.1016/j.tet.2005.07.054
http://www.eprints.iicb.res.in/330/