ICAR Research Data Repository for Knowledge Management
Stereoselective Synthesis of Chiral Oxepanes and Pyrans through Intramolecular Nitrone Cycloaddition in Organized Aqueous Media
EPrints@IICB
View Archive Info| Field | Value | |
| Title |
Stereoselective Synthesis of Chiral Oxepanes and Pyrans through Intramolecular Nitrone Cycloaddition in Organized Aqueous Media
|
|
| Creator |
Chatterjee, Amrita
Bhattacharya, Pranab K |
|
| Subject |
Chemistry
|
|
| Description |
A highly stereoselective surfactant-catalyzed intramolecular nitrone (formed by dehydration in water) cycloaddition in aqueous media leading to exclusive formation of a single isomer is reported. Either oxepane or pyran is formed from 3-O-allyl furanoside derivatives, which constitute the framework of a large number of biologically active compounds. Therefore, the environmentally friendly, efficient, and highly stereoselective syntheses of these chiral intermediates are still a meaningful pursuit. |
|
| Date |
2006
|
|
| Type |
Article
PeerReviewed |
|
| Format |
application/pdf
|
|
| Identifier |
http://www.eprints.iicb.res.in/398/1/JOURNAL_OF_ORGANIC_CHEMISTRY%2C__71(_1)%2C_345%2D348_[143].pdf
Chatterjee, Amrita and Bhattacharya, Pranab K (2006) Stereoselective Synthesis of Chiral Oxepanes and Pyrans through Intramolecular Nitrone Cycloaddition in Organized Aqueous Media. The Journal of Organic Chemistry, 71. pp. 345-348. |
|
| Relation |
http://dx.doi.org/10.1021/jo051414j CCC: $33.50
http://www.eprints.iicb.res.in/398/ |
|