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General Route to 4a-Methylhydrofluorene Diterpenoids: Total Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B, (()-Dichroanal B, and (()-Dichroanone

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Title General Route to 4a-Methylhydrofluorene Diterpenoids: Total
Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B,
(()-Dichroanal B, and (()-Dichroanone
 
Creator Banerjee, Mainak
Mukhopadhyay, Ranjan
Achari, Basudeb
Banerjee, Asish Kr
 
Subject Chemistry
 
Description A general and convergent route for the synthesis of the 4a-methylhydrofluorene diterpenoids has been
established through a common hexahydrofluorenone intermediate (10) obtained via Pd(0)-catalyzed
reductive cyclization of a substituted 2-(2-bromobenzyl) methylene cyclohexane (13). The strategy has
been successfully utilized for the synthesis of (()-taiwaniaquinones D (3) and H (5), (()-taiwaniaquinol
B (1), (()-dichroanal B (7), and (()-dichroanone (8).
 
Date 2006
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/401/1/JOURNAL_OF_ORGANIC_CHEMISTRY%2C_71(_7)%2C_2787%2D2796_[113].pdf
Banerjee, Mainak and Mukhopadhyay, Ranjan and Achari, Basudeb and Banerjee, Asish Kr (2006) General Route to 4a-Methylhydrofluorene Diterpenoids: Total Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B, (()-Dichroanal B, and (()-Dichroanone. Journal of Organic Chemistry , 71 (7). pp. 2787-2796.
 
Relation http://dx.doi.org/10.1021/jo052589w
http://www.eprints.iicb.res.in/401/