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New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds

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Field Value
 
Title New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds
 
Creator Maiti, Dilip K
Bhattacharya, Pranab K
 
Subject Chemistry
 
Description (S)-(+)-2-(a-Hydroxybenzyl)benzimidazole (1) and (S)-(-)-2-
benzimidazole-1 -ethanol (2) were synthesised and converted to chiral borohydrides
which reduced prochiral ketones to the corresponding chiral alcohols in high yields
(80 to loo%, e.e. 42 to 95%). This is the first report of sodium borohydride
modified by 1,2-amino alcohol.
 
Date 1998
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/824/1/SYNTHETIC_COMMUNICATIONS%2C_28(_1)%2C_99%2D108[63].pdf
Maiti, Dilip K and Bhattacharya, Pranab K (1998) New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds. Synthetic Communications, 28 (1). pp. 99-108.
 
Relation http://dx.doi.org/10.1080/00397919808005078
http://www.eprints.iicb.res.in/824/