Record Details

An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel Tetrahydro-β-Carboline Glycosides

EPrints@IICB

View Archive Info
 
 
Field Value
 
Title An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel
Tetrahydro-β-Carboline Glycosides
 
Creator Pradhan, Prasun K
Nandi, Debkumar
Pradhan, Soma
Jaisankar , P
Giri, V S
 
Subject Chemistry
 
Description An unusual kinetic approach to the Pictet–Spengler reaction
was investigated, in which L- or D-tryptophan methyl ester
reacted with aldehydes of 1,2-O-cyclohexylidene-3-allyloxy-α-Dxylofuranose,
yielding exclusively the cis or trans diastereomer of
tetrahydro-β-carboline glycoside, respectively, with complete
stereocontrol
 
Date 2013
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/1821/1/SYNLETT_24__(_1)___85%2D89_;2013[11].pdf
Pradhan, Prasun K and Nandi, Debkumar and Pradhan, Soma and Jaisankar , P and Giri, V S (2013) An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel Tetrahydro-β-Carboline Glycosides. Synlett, 24 (1). pp. 85-89.
 
Relation http://dx.doi.org/10.1055/s-0032-1317632;
http://www.eprints.iicb.res.in/1821/