ICAR Research Data Repository for Knowledge Management
Palladium(0)-Catalyzed Intramolecular Decarboxylative Allylation of Ortho Nitrobenzoic Esters
EPrints@IICB
View Archive Info| Field | Value | |
| Title |
Palladium(0)-Catalyzed Intramolecular Decarboxylative Allylation of Ortho Nitrobenzoic Esters
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| Creator |
Hossian, Asik
Singha, Shantanu Jana, Ranjan Jana |
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| Subject |
Chemistry
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| Description |
A Pd/Ag bimetallic system has been developed for the decarboxylative allylation of ortho-nitrobenzoic esters in an intramolecular fashion. In contrast to the typical sp2−sp3 cross-coupling approach which requires air and moisture sensitive preformed organometallic reagents, we provide an alternative route to the synthesis of ortho-allyl nitroarenes from the corresponding ortho-nitrobenzoic acid derivatives. The reaction proceeds through a mechanistically distinct decarboxylative metalation pathway. A cooperative reactivity of palladium and silver is crucial for the reaction outcome. |
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| Publisher |
American Chemical Society
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| Date |
2015
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/2161/1/ORGANIC_LETTERS__V16__)_15)3934%2D3937;2014[73].pdf
Hossian, Asik and Singha, Shantanu and Jana, Ranjan Jana (2015) Palladium(0)-Catalyzed Intramolecular Decarboxylative Allylation of Ortho Nitrobenzoic Esters. Organic Letters, 16 (15). pp. 3934-3937. |
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| Relation |
http://dx.doi.org/10.1021/ol5017349
http://www.eprints.iicb.res.in/2161/ |
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