Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions
EPrints@IICB
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Title |
Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions
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Creator |
Chaudhari, Tohasib Yusub
Hossian, Asik Manna, Manash Kumar Jana, Ranjan |
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Subject |
Chemistry
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Description |
Heck arylation with allylic alcohol is extremely challenging due to chemo-, regio-, and stereoselective scrambling. Here we report a mild protocol for the alcohol selective β- and α-arylation of allylic and cinnamyl alcohols respectively with aryldiazonium salts. The steric and electronic parameters of the alkene play a prominent role in the regioselectivity |
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Date |
2015
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Type |
Article
PeerReviewed |
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Format |
application/pdf
application/pdf |
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Identifier |
http://www.eprints.iicb.res.in/2246/1/ORGANIC_%26_BIOMOLECULAR_CHEMISTRY__V.__13__(_17_)_4841%2D4845_;2015[89].pdf
http://www.eprints.iicb.res.in/2246/2/ORGANIC_%26_BIOMOLECULAR_CHEMISTRY__V.__13__(_17_)_4841%2D4845_;2015[89].pdf Chaudhari, Tohasib Yusub and Hossian, Asik and Manna, Manash Kumar and Jana, Ranjan (2015) Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions. Organic & Biomolecular Chemistry, 13 (17). pp. 4841-4845. |
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Relation |
http://dx.doi.org/10.1039/c5ob00235d
http://www.eprints.iicb.res.in/2246/ |
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