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Asymmetric Synthesis Of Troger's Base Analogues And Studies In Molecular Recognition

Electronic Theses of Indian Institute of Science

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Field Value
 
Title Asymmetric Synthesis Of Troger's Base Analogues And Studies In Molecular Recognition
 
Creator Bag, Braja Gopal
 
Subject Organic Chemistry
Amines - Synthesis
Nitrogen compounds - Synthesis
Troger's Base Analogues
Tweezers- Synthesis
 
Description Troger's base was the first amine to be resolved where the chirality was due to solely very high inversion barrier around nitrogen atom. Though the molecule was known for over a century, work done during the past decade has shown that Troger's base and its analogues could be used as chiral solvating agent, DNA binding ligand and for the construction of biomimetic molecular receptors and clathrare hosts. Asymmetric synthesis of the Troger’s base analogues has also been achieved recently. Because of the rigid, 'V'-shaped chiral nature of this molecule, there is growing interest for the use of this unit in the design of potential host systems. This section briefly describes the chemistry of Troger's base developed over a century.
 
Publisher Indian Institute of Science
 
Contributor Maitra, Uday
 
Date 2005-04-25T05:43:59Z
2005-04-25T05:43:59Z
2005-04-25T05:43:59Z
1994-09
 
Type Electronic Thesis and Dissertation
 
Format 6863965 bytes
application/pdf
 
Identifier http://etd.iisc.ernet.in/handle/2005/105
null
 
Language en
 
Rights I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertation.