<p>Tamarind water catalyzed improved synthesis of 2,2ʹ-arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) derivatives: A green approach</p>
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Title Statement |
<p>Tamarind water catalyzed improved synthesis of 2,2ʹ-arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) derivatives: A green approach</p> |
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Added Entry - Uncontrolled Name |
Pal, Rammohan ; Acharya Jagadish Chandra Bose College UGC, New Delhi |
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Uncontrolled Index Term |
Tamarind water, catalysis, condensation reaction, green synthesis, 2,2ʹ-arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) |
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Summary, etc. |
<p style="text-align: justify;">The reaction of 5,5-dimethyl-1,3-cyclohexanedione (dimedone) with various aromatic aldehydes catalyzed by tamarindwater produces 2,2ʹ-arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) derivatives in 85-98% yield underwater bath heating at 60°C. Xanthene derivatives as cyclized products have not been obtained by this procedure.This method provides several advantages such as environmental friendliness, high yields and simple work-up procedure.The product is purified by simple filtration followed by crystallization with ethanol and drying processes.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section B (IJC-B) 2020-02-11 16:52:26 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCB/article/view/28053 |
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Data Source Entry |
Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 2 (2020): Indian Journal of Chemistry -Section B |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCB/article/download/28053/465486756 http://op.niscair.res.in/index.php/IJCB/article/download/28053/465486757 http://op.niscair.res.in/index.php/IJCB/article/download/28053/465486758 http://op.niscair.res.in/index.php/IJCB/article/download/28053/465486759 |
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