Stereoselective synthesis towards (+)-trans-kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide
NOPR - NISCAIR Online Periodicals Repository
View Archive InfoField | Value | |
Title |
Stereoselective synthesis towards (+)-trans-kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide
|
|
Creator |
Chowhan, L Raju
Raghavan, Sadagopan |
|
Subject |
α-Chloro sulfide
Mukaiyama type reaction Oxa-Michael addition (+)-trans-Kumausyne 2-trimethylsiloxy furan |
|
Description |
1199-1205
A stereoselective synthesis towards (+)-trans-kumausyne is disclosed. The key steps of the synthesis include stereoselective C-C formation employing vinylogous Mukaiyama type reaction of an α-chloro sulfide with 2-trimethylsiloxy furan and base-catalyzed isomerization followed by intramolecular oxa-Michael reaction. |
|
Date |
2020-10-05T08:55:57Z
2020-10-05T08:55:57Z 2020-08 |
|
Type |
Article
|
|
Identifier |
0975-0983(Online); 0376-4699(Print)
http://nopr.niscair.res.in/handle/123456789/55437 |
|
Language |
en_US
|
|
Rights |
CC Attribution-Noncommercial-No Derivative Works 2.5 India
|
|
Publisher |
NISCAIR-CSIR, India
|
|
Source |
IJC-B Vol.59B(08) [August 2020]
|
|